Product ID:KROVAR I DF HERBICIDE
MSDS Date:02/17/2000
FSC:6840
NIIN:00-001-7710
Status Code:A
MSDS Number: CKZBM

DUPONT (AGRICULTURAL PRODUCTS)

1007 MARKET STREET
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637

Info Phone: 800-441-7515

Cage: UO281

TIMBERLAND ENTERPRISES INC

557 MONTICELLO, AR 71655 US

Telephone: 501-367-8561

Cage: 1HB45

BROMACIL (5-BROMO-3-SEC-BUTYL-6-METHYLURACIL)

CAS: 314-40-9

RTECS: YQ9100000

DIURON (3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA)

CAS: 330-54-1

RTECS: YS8925000

ACGIH TLV: 10 MG/M3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

INERT INGREDIENTS

LD50 LC50 Mixture:ACUTE ORAL (RAT) LD50 >2,500 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUTION: HARMFUL IF SWALLOWED. HARMFUL
IF ABSORBED THROUGH SKIN. CAUSES EYE IRRITATION. SKIN IRRITATION
AND SENSITIZATION. - IN SKIN IRRITATION TESTS WITH RABBITS, PRODUCT
WAS A PRIMARY SKIN IRRITANT. IT WAS NOT A SKIN SENSITIZER IN TESTS
WITH GUINEA PIGS. EYE (RABBIT) - A MILD EYE IRRITANT WITH EYES
NORMAL WITHIN 7 DAYS AFTER TREATMENT.
Explanation of Carcinogenicity:NONE OF THE COMPONENTS PRESENT IN THIS
MATERIAL AT CONCENTRATIONS EQUAL TO OR GREATER THAN 0.1% ARE LISTED
BY IARC, NTP, OSHA OR ACGIH AS A CARCINOGEN.
Effects of Overexposure:SKIN CONTACT MAY INITIALLY CAUSE IRRITATION OR
RASH, EYE CONTACT MAY INITIALLY INCLUDE IRRITATION, TEARING, OR
BLURRING OF VISION. OVEREXPOSURE BY INHALATION, INGESTION, SKIN OR
EYE CONTACT MAY INITI ALLY INCLUDE: SKIN IRRITATION WITH DISCOMFORT
OR RASH; EYE IRRITATION WITH DISCOMFORT, TEARING, OR BLURRING OF
VISION; LIVER ENLARGEMENT; SPLEEN AND THYROID EFFECTS; RED BLOOD
CELL DESTRUCTION; OR RED UCTION OF THE BLOOD'S OXYGEN CARRYING
CAPACITY WITH CYANOSIS (BLUISH DISCOLORATION), WEAKNESS, OR
SHORTNESS OF BREATH.

First Aid:INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. CALL A PHYSICIAN. SKIN CONTACT: IN CASE OF CONTACT,
IMMEDIATELY WASH SKIN WITH SOAP AND WATER. WASH CONTAMINATED
CLOTHING BEFORE REUSE. EYE CONTACT: IN CASE OF CONTACT, IMMEDIATELY
FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL A
PHYSICIAN. INGESTION: I F SWALLOWED, IMMEDIATELY GIVE 2 GLASSES OF
WATER AND INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. CALL A PHYSICIAN.

Autoignition Temp:=420.C, 788.F
Lower Limits:0.135 G/L
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CO2. MAY BE
IGNITED BY HEAT OR OPEN FLAME.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. WEAR
FULL PROTECTIVE EQUIPMENT. USE WATER SPRAY. RUNOFF FROM FIRE
CONTROL MAY BE A POLLUTION HAZARD.
Unusual Fire/Explosion Hazard:IF AREA IS HEAVILY EXPOSED TO FIRE AND IF
CONDITIONS PERMIT, LET FIRE BURN ITSELF OUT SINCE WATER MAY
INCREASE THE CONTAMINATION HAZARD.

Spill Release Procedures:SAFEGUARDS: REVIEW FIRE FIGHTING MEASURES AND
HANDLING (PERSONNEL) SECTIONS BEFORE PROCEEDING WITH CLEAN-UP. USE
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN-UP. SHOVEL
OR SWEEP UP. NEVER RE TURN TO CONTAINER FOR REUSE. SCOOP INTO BAGS
OR BOXES WITH PLASTIC OR ALUMINUM SHOVEL. IF SPILL AREA IS ON
GROUND NEAR VALUABLE PLANTS OR TREES, REMOVE TOP 2 INCHES OF SOIL
AFTER INITIAL CLEAN UP.

Handling and Storage Precautions:STORE IN A WELL VENTILATED PLACE. KEEP
CONTAINER TIGHTLY CLOSED. DO NOT STORE OR CONSUME FOOD, DRINK OR
TOBACCO IN AREAS WHERE THEY MAY BECOME CONTAMINATED WITH THIS
MATERIAL. USERS SHOULD: WASH HANDS BEFORE EATING, DRINKING,
CHEWING GUM, USING TOBACCO OR USING THE TOILET.
Other Precautions:AVOID BREATHING VAPORS OR MIST, AVOID BREATHING DUST.
AVOID CONTACT WITH EYES, SKIN, OR CLOTHING. WASH THROUGHLY AFTER
HANDLING. WASH CLOTHING AFTER USE. DO NOT STORE OR CONSUME FOOD,
DRINK OR TOBACCO IN AREAS WHERE THEY MAY BECOME CONTAMINATED WITH
THIS MATERIAL.

Respiratory Protection:ALWAYS FOLLOW LABEL INSTRUCTIONS WHEN USING THIS
PRODUCT. PPE REQUIRED FOR EARLY ENTRY TO TREATED AREAS THAT IS
PERMITTED UNDER THE WORKER PROTECTION STANDARD AND THAT INVOLVES
ANYTHING THAT HAS BEEN TREATED, SUCH AS PLANTS, SOIL, OR WATER.
Ventilation:USE ONLY WITH ADEQUATE VENTILATION. KEEP CONTAINER TIGHTLY
CLOSED.
Protective Gloves:WATERPROOF GLOVES.
Other Protective Equipment:LONG-SLEEVED SHIRT AND LONG PANTS.
WATERPROOF GLOVES, SHOES PLUS SOCKS, COVERALLS.
Supplemental Safety and Health
FOLLOW MANUFACTURER'S INSTRUCTIONS FOR CLEANING/MAINTAINING PPE. IF NO
SUCH INSTRUCTIONS FOR WASHABLES, USE DETERGENT AND HOT WATER. KEEP
AND WASH PPE SEPARATELY FROM OTHER LAUNDRY.

HCC:V7
Solubility in Water:DISPERSIBLE
Appearance and Odor:BROWN SOLID. ODOR: NONE

Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:STABLE AT NORMAL TEMPERATURES AND STORAGE
CONDITIONS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION, AND DISPOSAL
MUST BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE/PROVINCIAL,
AND LOCAL REGULATIONS. REMOVE NONUSABLE SOLID MATERIAL AND/OR
CONTAMINATED SOIL, FOR D ISPOSAL IN AN APPROVED AND PERMITTED
LANDFILL. DO NOT FLUSH TO SURFACE WATER OR SANITARY SEWER SYSTE M.

Toxicological Information:BROMACIL:THE COMPOUND IS A MODERATE SKIN
IRRITANT, IS A MILD TO MODERATE EYE IRRITANT, BUT IS NOT A SKIN
SENSITIZER. RABBITS ACUTELY EXPOSED VIA DERMAL ROUTE DEMONSTRATED
NO CLINICAL SIGNS OF TOXICITY , AND NO GROSS TISSUE CHANGES WERE
OBSERVED, AT THE HIGHEST PRACTICAL DOSE, 5,000 MG/KG. DIURON: THE
COMPOUND IS A SKIN IRRITANT, IS AN EYE IRRITANT, AND IS NOT A SKIN
SENSITIZER IN ANIMALS. TOXIC EF FECTS DESCRIBED IN ANIMALS FROM
SHORT EXPOSURES BY INHALATION, INGESTION, OR SKIN CONTACT INCLUDE:
BLOOD EFFECTS, SPLEEN EFFECTS, THYROID EFFECTS, METHEMOGLOBINEMIA,
AND NONSPECIFIC EFFECTS SUCH AS WE IGHT LOSS, ETC.

Transport Information:NOT REGULATED

SARA Title III Information:TITLE III HAZARD CLASSIFICATIONS SECTIONS
311, 312- ACUTE: YES, CHRONIC: YES, FIRE: NO, REACTIVITY: NO,
PRESSURE: NO. SARA/CERCLA REPORTABLE QUANTITY- DIURON (100 LBS).
Federal Regulatory Information:THIS PRODUCT IS REGISTERED AND
CONTROLLED UNDER EPA/FIFRA REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.